Ab. Pepperman et Jcw. Kuan, CONTROLLED-RELEASE FORMULATIONS OF ALACHLOR BASED ON CALCIUM ALGINATE, Journal of controlled release, 34(1), 1995, pp. 17-23
Granular controlled release formulations of alachlor were prepared fro
m sodium alginate-kaolin-linseed oil-herbicide slurries dropped onto c
alcium chloride to form spherical beads which were air-dried and evalu
ated for release rates in a static water extraction. These formulation
s gave considerably slower release of alachlor than a commercial formu
lation and/or the alginate formulation without oil. Factors affecting
the rate of release included aging of the dried formulation and the ra
tio of oil/herbicide in the formulation. The size of the beads had no
appreciable effect on the rate of release and several oils, including
canola, corn, olive, safflower, peanut, soybean, and sunflower gave si
milar release rates to linseed oil formulations for alachlor. The use
of lignin in combination with alginate also produced a granular formul
ation with reduced release rates.