New 4,4'-bis(arylglyoxaloyl)benzophenones were prepared on the basis o
f 4,4'-diiodobenzophenone-a derivative of chloral. The reaction betwee
n 4,4'-bis(arylglyoxaloyl)benzophenones and aromatic bis(o-phenylenedi
amine)s leads to poly(arylquinoxaline)s containing phenyl, diphenyl, d
iphenyl ether, diphenyl thioether, and benzophenone side groups. The r
esulting polymers combine enhanced solubility and high thermal charact
eristics. The films were prepared and their mechanical and dielectric
properties were studied.