A new adsorption-desorption method for determining the efficiency of H
-2 thermal dissociation on a hot metal surface is proposed. The result
s obtained by means of this method confirm the validity of Langmuir's
equation describing H-2 atomization on a hot tungsten surface within t
he temperature range 1020-1315 K at a H-2 pressure of 2 x 10(-3) torr.
A comparison of our results with Brennan-Fletcher's equation gives lo
wer values for the efficiency of H-2 atomization.