Surface photovoltage spectroscopy (SPS) with a modified Kelvin method
and photoconductivity (PC) measurements have been carried out for epit
axial GaAs-GaAs:Si layers deposited by a MOCVD method on the semi-insu
lated GaAs substrate compensated with chromium. The substrate orientat
ion was (100). The silicon concentration in the doped epitaxial layer
amounted to 5.4 x 10(16) cm(-3). The measurements were carried out at
a temperature of 83 K. The existence of three types of doping levels i
n the bulk with energies E(1) = 0.83 eV, E(2) = 1.17 eV and E(3) = 1.4
3 eV below the bottom of the conduction band, and two types of surface
levels with energies E(t4) = 0.05 eV and E(t5) = 0.19 eV, also below
the bottom of the conduction band, have been stated. The value of the
surface voltage barrier V-s(o) = 0.22 eV at 83 K has been measured and
the influence of the photoadsorption of the rest gases in the measuri
ng chamber on ifs height has been investigated. The energy of the band
gap at 83 K, equal to 1.51 eV, and its temperature coefficient alpha
= 3.3 x 10(-4) eV/K, have been determined.