RADICAL COPOLYMERIZATION OF N-VINYLPYRROLIDONE WITH N-VINYLFORMAMIDE

Citation
Ye. Kirsh et al., RADICAL COPOLYMERIZATION OF N-VINYLPYRROLIDONE WITH N-VINYLFORMAMIDE, Vysokomolekularnye soedinenia. Seria A, 38(11), 1996, pp. 1905-1908
Citations number
8
Categorie Soggetti
Polymer Sciences
ISSN journal
05075475
Volume
38
Issue
11
Year of publication
1996
Pages
1905 - 1908
Database
ISI
SICI code
0507-5475(1996)38:11<1905:RCONWN>2.0.ZU;2-2
Abstract
Radical copolymerization of N-vinylpyrrolidone with N-vinylformamide i n isopropanol solution was studied. It was found that the reactivity r atios of these comonomers are both equal to unity. The mechanism of th e copolymerization was explained by assuming that the chain propagatio n involves N-vinylformamide molecules in the trans-conformation that a re associated by hydrogen bonding.