Ye. Kirsh et al., RADICAL COPOLYMERIZATION OF N-VINYLPYRROLIDONE WITH N-VINYLFORMAMIDE, Vysokomolekularnye soedinenia. Seria A, 38(11), 1996, pp. 1905-1908
Radical copolymerization of N-vinylpyrrolidone with N-vinylformamide i
n isopropanol solution was studied. It was found that the reactivity r
atios of these comonomers are both equal to unity. The mechanism of th
e copolymerization was explained by assuming that the chain propagatio
n involves N-vinylformamide molecules in the trans-conformation that a
re associated by hydrogen bonding.