Cs. So et al., TE-BEARING AND SE-BEARING EPITHERMAL AU-AG MINERALIZATION, PRASOLOVSKOYE, KUNASHIR ISLAND, KURIL ISLAND-ARC, Economic geology and the bulletin of the Society of Economic Geologists, 90(1), 1995, pp. 105-117
Au-Ag-Te-Se-bearing epithermal mineralization at Prasolovskoye, northw
est Kunashir Island, Kurils, occurs along fault zones developed within
a circular intrusive zone in Miocene to Quaternary age volcanic rocks
. The ores show complex textures and mineralogy and can be divided int
o three stages based on tectonic fracturing and mineral associations:
pyritic (I), polymetallic (II), and gold-silver (III). Stages I and II
occur as hydrothermal replacement zones, veins, and breccias and are
base metal sulfide rich without economic gold and silver grades. Fluid
inclusion and sulfur isotope data indicate that stages I and II forme
d from relatively high temperature (up to 340 degrees C) fluids with s
alinities of 1.2 to 5.5 wt percent NaCl equiv. Following intrusion of
rhyolitic dikes after stages I and II, gold-silver mineralization (sta
ge III) formed during the late Pliocene (based on a K-Ar age of 1.94 /- 0.10 Ma for a gold-bearing, adularia-rich vein sample). Vein-relate
d, wall-rock alteration zones (0.5-2.5 m thick) occur along stage III
veins, overprinting pervasive propylitic assemblages, and consist main
ly of silicification and sericitization. Stage III ore mineralization
is composed of four substages which show a progressive change in miner
alogy with increasing paragenetic time: substage IIIA, bismuthinite-ca
ssiterite-quartz; IIIB, polysulfide quartz; IIIC, telluride quartz; II
ID, calcite-adularia-quartz. Each substage contains economic concentra
tions of gold and silver and shows distinct mineral assemblages with s
pecific Au/Ag ratios and gold fineness values. Telluride quartz veins
(usually 1-2 m thick) of substage IIIC are most typical of economic ve
ins at Prasolovskoye and show characteristics of adularia-sericite-typ
e deposits. Ore minerals in this substage consist of sulfides, telluri
des, selenides, sulfosalts, native metals, sulfates, oxides, hydroxide
s, and tellurates. Fluid inclusion data indicate that the main Au-Ag-T
e-Se mineralization during substage IIIC occurred at temperatures betw
een 150 degrees and 245 degrees C from low-salinity (0.4-1.6 wt % NaCl
equiv) fluids. Gold deposition was most likely the result of boiling
of hydrothermal fluids. Measured and calculated O and II isotope compo
sitions of stage III fluids (delta(18)O = -4.7 to -9.4 parts per thous
and; delta D = -80 to -83 parts per thousand) indicate meteoric water
dominance during the Au-Ag-Te-Se mineralizing event.