CYCLODIMERIZATION OF BICYCLO[2.2,1]HEPTA-2,5-DIENE IN THE PRESENCE OFRHODIUM-CONTAINING ZEOLITE CATALYSTS

Authors
GOLDSHLEGER NF AZBEL BI ISAKOV YI SHPIRO ES MINACHEV KM
Citation
Nf. Goldshleger et al., CYCLODIMERIZATION OF BICYCLO[2.2,1]HEPTA-2,5-DIENE IN THE PRESENCE OFRHODIUM-CONTAINING ZEOLITE CATALYSTS, Russian chemical bulletin, 43(11), 1994, pp. 1802-1808
Citations number
22
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
43
Issue
11
Year of publication
1994
Pages
1802 - 1808
Database
ISI
SICI code
1066-5285(1994)43:11<1802:COBITP>2.0.ZU;2-S
Abstract
It has been shown that norbornadiene is dimerized in the presence of r hodium-containing zeolite catalysts, forming hexacyclic [4+2]dimers pr eferentially. The effect of the structure and the method of preparatio n and pretreatment of the catalysts on their activity and selectivity in norbornadiene cycloaddition was studied. The influence of the above parameters on the change in the electronic state of rhodium in the co urse of the reaction was also investigated.