MACROMOLECULAR DESIGN OF NEW CATIONIC POLYELECTROLYTES

Methods were elaborated for the synthesis of new monomers, derivatives of diallylguanidine and macromers, which contain fragments of polytet rahydrofuran and diallylic nitrogen-containing end groups (diallylamin e, alkyldiallylammonium, diallylguanidine both in base and acetate for ms). Alkylation of a macromer with a diallylamine end group was carrie d out with methyl iodide in various organic solvents. The possibility of synthesis of diallylguanidine acetate homopolymer as well as its st atistical copolymer with diallyldimethylammonium chloride was shown. F or the first time, block copolymers based on synthesized macromers wer e obtained.