REACTION OF TRIMETHYLTIN 1-PENTANETHIOLATE WITH N-CHLORO-N-SODIUM-4-CHLOROBENZENESULFONAMIDE

Authors
SHCHERBAKOV VI STOLYAROVA NE
Citation
Vi. Shcherbakov et Ne. Stolyarova, REACTION OF TRIMETHYLTIN 1-PENTANETHIOLATE WITH N-CHLORO-N-SODIUM-4-CHLOROBENZENESULFONAMIDE, Russian chemical bulletin, 43(11), 1994, pp. 1913-1915
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
43
Issue
11
Year of publication
1994
Pages
1913 - 1915
Database
ISI
SICI code
1066-5285(1994)43:11<1913:ROT1WN>2.0.ZU;2-7
Abstract
The reaction of trimethyltin 1-pentanethiolate with N-chloro-N-sodium- 4-chlorobenzenesulfonamide proceeds in anhydrous methanol via the init ial cleavage of the tin-sulfur bond (desulfurization process) and subs equent imination of the sulfenylamide group of yl-N-(1-pentyl)sulfenyl -4-chlorobenzenesulfonamide with a second molecule of the chloroamide.