SYNTHESIS AND CRYSTAL-STRUCTURE OF PH(3)LN(THF)(3) (LN=ER, TM)

Authors
BOCHKAREV LN STEPANTSEVA TA ZAKHAROV LN FUKIN GK YANOVSKY AI STRUCHKOV YT
Citation
Ln. Bochkarev et al., SYNTHESIS AND CRYSTAL-STRUCTURE OF PH(3)LN(THF)(3) (LN=ER, TM), Organometallics, 14(5), 1995, pp. 2127-2129
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
14
Issue
5
Year of publication
1995
Pages
2127 - 2129
Database
ISI
SICI code
0276-7333(1995)14:5<2127:SACOP(>2.0.ZU;2-9
Abstract
Triphenyllanthanoids Ph(3)Ln(THF)(3) (Ln = Er (1), Tm (2)) were synthe sized in THF by reaction of metallic lanthanoids with Ph(2)Hg or Ph(3) Bi in the presence of catalytic amounts of LnI(3). The X-ray diffracti on studies of 1 and 2 have shown that these species represent monomeri c complexes with a distorted fac-octahedral arrangement of ligands aro und the Ln atom.