ORGANOMETALLIC CHEMISTRY OF AMBIDENT DIANIONS - REACTIONS OF ORGANOSILICON DIHALIDES WITH ACETONE DIANIONS - REMARKABLE DIFFERENCE IN REACTIVITY BETWEEN DIORGANODICHLOROSILANES AND DIORGANODIFLUOROSILANES

Authors
SEYFERTH D WANG T OSTRANDER RL RHEINGOLD AL
Citation
D. Seyferth et al., ORGANOMETALLIC CHEMISTRY OF AMBIDENT DIANIONS - REACTIONS OF ORGANOSILICON DIHALIDES WITH ACETONE DIANIONS - REMARKABLE DIFFERENCE IN REACTIVITY BETWEEN DIORGANODICHLOROSILANES AND DIORGANODIFLUOROSILANES, Organometallics, 14(5), 1995, pp. 2136-2138
Citations number
8
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
14
Issue
5
Year of publication
1995
Pages
2136 - 2138
Database
ISI
SICI code
0276-7333(1995)14:5<2136:OCOAD->2.0.ZU;2-A
Abstract
The [CH2C(O)CPh(2)](2-) dianion reacted with R(2)SiCl(2) (R = Ph, CH3, Et) to give cyclic products of type 5, but with R(2)SiF(2) 4 (R = Ph, Et) was formed. The structures of 5 and 4 (R = Ph) were determined by single-crystal X-ray diffraction. A reason for the difference in the regioselectivity of the reactions of the dianion with R(2)SiCl(2) and R(2)SiF(2) is suggested.