SULFURATED BOROHYDRIDE USED AS BLEACHING CHEMICAL ON A SOFTWOOD TMP

Citation
S. Robert et al., SULFURATED BOROHYDRIDE USED AS BLEACHING CHEMICAL ON A SOFTWOOD TMP, Research of chemical intermediates, 21(3-5), 1995, pp. 563-576
Citations number
17
Categorie Soggetti
Chemistry
ISSN journal
09226168
Volume
21
Issue
3-5
Year of publication
1995
Pages
563 - 576
Database
ISI
SICI code
0922-6168(1995)21:3-5<563:SBUABC>2.0.ZU;2-N
Abstract
We studied the bleaching potential of a highly reductive chemical: sul furated borohydride, also known as the Lalancette's reagent, on a spru ce/fir softwood TMP. The influences of reaction time, temperature, pul p consistency and reactant concentration on pulp brightness were studi ed. A very fast reaction was observed, along with an adverse effect of high temperature on brightness. High reactant concentration increases brightness gain. Sulfurated borohydride was compared to sodium hydros ulfite and sodium borohydride. The Lalancette's reagent bleaches pulp to the same level as sodium hydrosulfite, but lowers the yellowness of the pulp to a greater extent.