LINEAR TITANOXANES VIA THE ASSEMBLING OF BRIDGING AND TERMINAL OXO-TITANIUM(IV) FRAGMENTS

Authors
GALLO E SOLARI E FRANCESCHI F FLORIANI C CHIESIVILLA A RIZZOLI C
Citation
E. Gallo et al., LINEAR TITANOXANES VIA THE ASSEMBLING OF BRIDGING AND TERMINAL OXO-TITANIUM(IV) FRAGMENTS, Inorganic chemistry, 34(10), 1995, pp. 2495-2496
Citations number
27
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
34
Issue
10
Year of publication
1995
Pages
2495 - 2496
Database
ISI
SICI code
0020-1669(1995)34:10<2495:LTVTAO>2.0.ZU;2-G
Abstract
The solvent-dependent reassembling of a conventional dimeric [Ti-O-Ti] unit into a chainlike titanoxane under ionization conditions is repor ted. The titanoxane is the polymeric form of the tetrameric sequence [ Ti=O-Ti-O-Ti-O=Ti] containing both the titanyl unit and the mu-oxo dim er, polymerization being achieved by a sharing of the oxygen atoms fro m the Schiff base ligand.