TRANSIENT ABSORPTION AND VIBRATIONAL-RELAXATION DYNAMICS OF THE LOWEST EXCITED SINGLET-STATE OF PYRENE IN SOLUTION

Citation
P. Foggi et al., TRANSIENT ABSORPTION AND VIBRATIONAL-RELAXATION DYNAMICS OF THE LOWEST EXCITED SINGLET-STATE OF PYRENE IN SOLUTION, Journal of physical chemistry, 99(19), 1995, pp. 7439-7445
Citations number
22
Categorie Soggetti
Chemistry Physical
ISSN journal
00223654
Volume
99
Issue
19
Year of publication
1995
Pages
7439 - 7445
Database
ISI
SICI code
0022-3654(1995)99:19<7439:TAAVDO>2.0.ZU;2-M
Abstract
The spectrum of highly excited electronic states of pyrene in n-octane solution and the relaxation processes in the S-1 singlet state are in vestigated by femtosecond transient absorption spectroscopy. Three dif ferent UV excitation wavelengths (360, 307, and 290 nm) are utilized t o excite the molecule at the edge of the S-1 <-- S-0 transition and to higher S-n <-- S-0 transitions. The buildup of S-1 population has bee n observed to be completed in the first 2 ps, with a time constant of 300-400 fs, depending on the excitation wavelength. The evolution of t he absorption spectra on a larger time scale is attributed to the vibr ational cooling in the S-1 state; its rate corresponds to an exponenti al relaxation with time constant of about 4 ps. The evidence of the fo rmation of pyrene excimer at long time delays in highly concentrated s olutions is reported.