SYNTHESIS AND GLYCOSYLATING PROPERTIES OF KETOPYRANOSYL DONORS

Authors
HESKAMP BM VEENEMAN GH VANDERMAREL GA VANBOECKEL CAA VANBOOM JH
Citation
Bm. Heskamp et al., SYNTHESIS AND GLYCOSYLATING PROPERTIES OF KETOPYRANOSYL DONORS, Tetrahedron, 51(19), 1995, pp. 5657-5670
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
51
Issue
19
Year of publication
1995
Pages
5657 - 5670
Database
ISI
SICI code
0040-4020(1995)51:19<5657:SAGPOK>2.0.ZU;2-2
Abstract
The preparation of heptulopyranosyl donors 13-15, 28, 29 and 3-octulop yranosyl donors 34, 35, having a non-participating group at C-3 or C-4 , respectively, is described. Glycosylations of various accepters with these donors gave exclusively cc-linked ketosides. On the other hand, condensation of 3-O-benzoyl heptulopyranosyl donor 19 with art accept or furnished an anomeric mixture of ketodisaccharides.