PRECISE MEASUREMENT OF CHLORINE ISOTOPES BASED ON CS2CL-SPECTROMETRY(BY THERMAL IONIZATION MASS)

Citation
Yk. Xiao et al., PRECISE MEASUREMENT OF CHLORINE ISOTOPES BASED ON CS2CL-SPECTROMETRY(BY THERMAL IONIZATION MASS), Analytical letters, 28(7), 1995, pp. 1295-1304
Citations number
7
Categorie Soggetti
Chemistry Analytical
Journal title
ISSN journal
00032719
Volume
28
Issue
7
Year of publication
1995
Pages
1295 - 1304
Database
ISI
SICI code
0003-2719(1995)28:7<1295:PMOCIB>2.0.ZU;2-C
Abstract
An improved procedure for precise measurement of chlorine isotope rati os in geological samples based on Cs2Cl+ ion by thermal ionization mas s spectrometry is reported. Using this procedure the Cl-37/Cl-35 ratio of NIST SRM 975 is determined to be 0.318929 +/- 0.000028(1 sigma) wi th a precision of 0.009%(1 sigma). The procedure has been successfully applied to study the variation of chlorine isotopic compositions in s eawater and to determine atomic weight of chlorine.