CATIONIC COMPLEXES OF DIORGANOTIN(IV) DERIVATIVES - THE CRYSTAL-STRUCTURE OF IS[1-METHYL-2(3H)-IMIDAZOLINETHIONE]DIETHYLTIN(IV) NITRATE

Authors
CASAS JS MARTINEZ EG GONZALEZ AS SORDO J CASELLATO U GRAZIANI R RUSSO U
Citation
Js. Casas et al., CATIONIC COMPLEXES OF DIORGANOTIN(IV) DERIVATIVES - THE CRYSTAL-STRUCTURE OF IS[1-METHYL-2(3H)-IMIDAZOLINETHIONE]DIETHYLTIN(IV) NITRATE, Journal of organometallic chemistry, 493(1-2), 1995, pp. 107-111
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
493
Issue
1-2
Year of publication
1995
Pages
107 - 111
Database
ISI
SICI code
0022-328X(1995)493:1-2<107:CCODD->2.0.ZU;2-W
Abstract
[SnEt(2)(Hmimt)(4)](NO3)(2) (Hmimt = 1-methyl-2(3H)-imidazolinethione) has been synthesized and characterized by mass spectrometry, IR, Rama n, Mossbauer, H-1, C-13 and Sn-119 NMR spectroscopy, and its crystal s tructure determined by X-ray crystallography. The coordination distanc es in the centrosymmetric octahedral cation are 2.163(5) Angstrom for Sn-C, and 2.729(2) and 2.752(2) Angstrom for Sn-S, and the [SnEt(2)(Hm imt)(4)](NO3)(2) units are interconnected by hydrogen bonds via their nitrate ions.