FROM PHOSPHAIMINES TO PHOSPHANES VIA TRANSIENT IMINOZIRCONIOPHOSPHORANES

Authors
LARRE C MAHIEU A IGAU A MAJORAL JP
Citation
C. Larre et al., FROM PHOSPHAIMINES TO PHOSPHANES VIA TRANSIENT IMINOZIRCONIOPHOSPHORANES, Journal of organometallic chemistry, 493(1-2), 1995, pp. 133-137
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
493
Issue
1-2
Year of publication
1995
Pages
133 - 137
Database
ISI
SICI code
0022-328X(1995)493:1-2<133:FPTPVT>2.0.ZU;2-L
Abstract
Transient iminozirconiophosphoranes 3a-3c, 8 and 13 can be generated f rom phosphaimines 2a-2e and zirconocenes derivative[Cp(2)ZrRR']. A pla usible reaction mechanism involving transfers of various groups from p hosphorus to zirconium is presented.