FIRST OPTICALLY-ACTIVE ORGANOMETALLIC FREE-RADICAL IN THE CYMANTRENE SERIES

Authors
MILUKOV VA SINYASHIN OG GINZBURG AG KONDRATENKO MA LOIM NM GUBSKAYA VP MUSIN RZ MOROZOV VI BATYEVA ES SOKOLOV VI
Citation
Va. Milukov et al., FIRST OPTICALLY-ACTIVE ORGANOMETALLIC FREE-RADICAL IN THE CYMANTRENE SERIES, Journal of organometallic chemistry, 493(1-2), 1995, pp. 221-222
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
493
Issue
1-2
Year of publication
1995
Pages
221 - 222
Database
ISI
SICI code
0022-328X(1995)493:1-2<221:FOOFIT>2.0.ZU;2-2
Abstract
Replacement of one CO ligand in the enantiomeric 2-methylcymantrenecar boxylic acid ester for a radical ligand PhS results in the preparation of stable and optically active odd-electron complex CH3C5H3COOCH3Mn(C O)(2)SPh] fully characterized by electron spin resonance, mass spectro scopy, UV-visible spectroscopy, IR spectroscopy and circular dichroism spectroscopy. This is the first example of an optically active organo metallic free radical.