IN-4(C(SIME(3))(3))(4) WITH IN-4-TETRAHED RON AND IN4SE4(C(SIME(3))(3))(4) WITH IN4SE4-HETEROCUBANE STRUCTURE

Authors
UHL W GRAUPNER R LAYH M SCHUTZ U
Citation
W. Uhl et al., IN-4(C(SIME(3))(3))(4) WITH IN-4-TETRAHED RON AND IN4SE4(C(SIME(3))(3))(4) WITH IN4SE4-HETEROCUBANE STRUCTURE, Journal of organometallic chemistry, 493(1-2), 1995, pp. 1-5
Citations number
41
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
493
Issue
1-2
Year of publication
1995
Pages
1 - 5
Database
ISI
SICI code
0022-328X(1995)493:1-2<1:IWIRAI>2.0.ZU;2-V
Abstract
The reaction of (InBr)-Br-I with LiC(SiMe(3))(3) . 2THF yields the In( I) alkyl In-4{C(SiMe(3))(3)}(4) 1 in 70% yield. 1 was characterized by a crystal structure determination showing a nearly undistorted In, te trahedron with mean In-In distances of 300.2(1) pm. Reaction of 1 with elemental Se gives In4Se4{C(SiMe(3))(3)}(4) 2 with a slightly distort ed In4Se4 hetero cubane structure.