Kv. Dvornikova et Ve. Platonov, THERMOLYTIC TRANSFORMATIONS OF POLYFLUOROORGANIC COMPOUNDS .31. COPYROLYSIS OF 4-CHLOROTETRAFLUOROBENZO TRICHLORIDE WITH CHLORODIFLUOROMETHANE, Russian chemical bulletin, 43(12), 1994, pp. 2079-2082
Copyrolysis of 4-chlorotetrafluorobenzotrichloride with chlorodifluoro
methane (as the source of difluorocarbene) gave hlorodifluoromethyl-al
pha-chlorohexafluorostyrene, 1,4-dichlorotetrafluorobenzene, and 4-(ch
lorodifluoromethyl)chlorotetrafluorobenzene along with 4-chloro-alpha-
chlorohexafluorostyrene. Possible routes for the formation of these pr
oducts have been offered.