THERMOLYTIC TRANSFORMATIONS OF POLYFLUOROORGANIC COMPOUNDS .31. COPYROLYSIS OF 4-CHLOROTETRAFLUOROBENZO TRICHLORIDE WITH CHLORODIFLUOROMETHANE

Citation
Kv. Dvornikova et Ve. Platonov, THERMOLYTIC TRANSFORMATIONS OF POLYFLUOROORGANIC COMPOUNDS .31. COPYROLYSIS OF 4-CHLOROTETRAFLUOROBENZO TRICHLORIDE WITH CHLORODIFLUOROMETHANE, Russian chemical bulletin, 43(12), 1994, pp. 2079-2082
Citations number
11
Categorie Soggetti
Chemistry
Journal title
ISSN journal
10665285
Volume
43
Issue
12
Year of publication
1994
Pages
2079 - 2082
Database
ISI
SICI code
1066-5285(1994)43:12<2079:TTOPC.>2.0.ZU;2-V
Abstract
Copyrolysis of 4-chlorotetrafluorobenzotrichloride with chlorodifluoro methane (as the source of difluorocarbene) gave hlorodifluoromethyl-al pha-chlorohexafluorostyrene, 1,4-dichlorotetrafluorobenzene, and 4-(ch lorodifluoromethyl)chlorotetrafluorobenzene along with 4-chloro-alpha- chlorohexafluorostyrene. Possible routes for the formation of these pr oducts have been offered.