Va. Dorokhov et al., CHELATE SYNTHESIS OF PYRAZOLYL(ETHOXYCARBONYL)KETENE ANIMALS, THE PRECURSORS OF FUNCTIONALIZED PYRAZOLO[1,5-C]PYRIMIDINES, Russian chemical bulletin, 43(12), 1994, pp. 2091-2094
A scheme for the preparation of novel synthetic reagents, pyrazolyl (e
thoxycarbonyl) ketene aminals, from acetyl(ethoxycarbonyl)ketene (N-be
nzoyl)aminal via its difluoroboron chelate is suggested. The possibili
ty of cyclization of the ketene aminals obtained into functionally sub
stituted pyrazolo[1,5-c]pyrimidines is shown.