INVESTIGATION OF THE THERMODYNAMIC PROPERTIES OF GAMMA-AL2O3

Citation
Qy. Chen et al., INVESTIGATION OF THE THERMODYNAMIC PROPERTIES OF GAMMA-AL2O3, Thermochimica acta, 253, 1995, pp. 33-39
Citations number
11
Categorie Soggetti
Chemistry Analytical
Journal title
ISSN journal
00406031
Volume
253
Year of publication
1995
Pages
33 - 39
Database
ISI
SICI code
0040-6031(1995)253:<33:IOTTPO>2.0.ZU;2-W
Abstract
The heat capacities of gamma-Al2O3 were measured from 50 to 700 degree s C using an HT1000 calorimeter. The heat of transformation gamma-Al2O 3 to alpha-Al2O3 was directly measured using an HT1500 calorimeter. Co mbination of these results with the values from the literature led to Delta(f)H(m)(theta) = -(1657.2 +/- 1.5) kJ mol(-1), S-m(theta) = (52.3 0 +/- 2.00) J mol(-1) K-1 and Delta(f)G(m)(theta) = -(1564.2 +/- 2.0) kJ mol(-1).