The practice and theory of permanent hair straightening are discussed.
Hair straightening as a cosmetic process is the reverse of hair wavin
g. It removes hair curliness and makes wavy hair straight. While it is
generally accepted that permanent hair straightening can be achieved
only at very high pH with strong alkali, we have observed that it can
also be achieved at neutral pH with lithium sale, or even at acidic pH
with resorcinol. Also, while some of these treatments do result in co
nsiderable loss of cystine, others leave the cystine entirely intact.
Lanthionine is produced in some cases, but is absent in others. It app
ears that the prime requirement for an effective hair straightening tr
eatment is to be able to induce supercontraction of the hair fiber. Ba
sed on these observations, a model is proposed to explain permanent ha
ir straightening in terms of certain molecular events such as chain fo
lding and alpha-beta transformation of the polypeptide in the hair ker
atin.