SYNTHESIS AND STRUCTURE STUDY OF THE COMPLEX [CU-2(MU-C2O4)(C10H8N2)(2)(H2O)(2)](C6H4COSO2N)(2) - CRYSTAL-STRUCTURE CONTAINING CU(II) BIPY OXALATO AND SACCHARIN

Authors
LI JM SUN JZ CHEN PC WU XT
Citation
Jm. Li et al., SYNTHESIS AND STRUCTURE STUDY OF THE COMPLEX [CU-2(MU-C2O4)(C10H8N2)(2)(H2O)(2)](C6H4COSO2N)(2) - CRYSTAL-STRUCTURE CONTAINING CU(II) BIPY OXALATO AND SACCHARIN, Crystal research and technology, 30(3), 1995, pp. 353-358
Citations number
12
Categorie Soggetti
Crystallography
Journal title
Crystal research and technology → ACNP
ISSN journal
02321300
Volume
30
Issue
3
Year of publication
1995
Pages
353 - 358
Database
ISI
SICI code
0232-1300(1995)30:3<353:SASSOT>2.0.ZU;2-B
Abstract
The title compound has been synthesized and its crystal structure dete rmined at room temperature. MW = 927.86, monoclinic, space group P2(1) /c, Z = 2, a = 9.283(1) Angstrom, b = 16.239(2) Angstrom, c = 12.209(1 )Angstrom, beta = 99.848(9)degrees. The crystal structure consists of repeated [Cu-2(mu-C2O4)(C10H8N2)(2) .(H2O)(2)](2) cations and non-coor dinated saccharin anions. Each copper ion is in a square pyrimidal env ironment with two oxalate oxygen and two bipyridine nitrogen atoms as a base and one water molecule at the apex. The two copper ions are bri dged by oxalato and the distance is 5.138 Angstrom.