Praseodymium-doped GaAs and Al0.3Ga0.7As epilayers grown on Semi-Insul
ating (SI) GaAs substrates by Liquid Phase Epitaxy (LPE) were first st
udied in this present work. Measurement techniques, such as microscopi
c observation, X-ray diffraction. Secondary Ion Mass Spectroscopy (SIM
S), and Hall measurement were employed. Layers doped with Pr resulted
in a mirror-like surface, except several high Pr-doped layers having d
roplet surfaces. Hall measurements reveal that the grown layers contai
ned p-type layers, carrier concentrations from 6.3 x 10(15) to 1.2 x 1
0(16) cm(-3), and from 6.3 x 10(15) to 3.5 x 10(16) cm(-3) for Pr-dope
d GaAs and Al0.3Ga0.7As epilayers, respectively. Although p-type condu
ction exists, in the light of electrical features, doping of Pr into t
he GaAs and Al0.3Ga0.7As growth melts is still considered to exhibit g
ettering properties rather than to become a new acceptor itself. Addit
ional photoluminescence examinations were taken. Their results also in
dicate that Pr-doped layers produce no new emission lines and support
the electrical observations.