REGIOSELECTIVE SYNTHESIS OF BETA,GAMMA-UNSATURATED ACIDS BY THE ELECTROCHEMICAL CARBOXYLATION OF ALLYLIC BROMIDES USING A REACTIVE-METAL ANODE

Authors
TOKUDA M KABUKI T KATOH Y SUGINOME H
Citation
M. Tokuda et al., REGIOSELECTIVE SYNTHESIS OF BETA,GAMMA-UNSATURATED ACIDS BY THE ELECTROCHEMICAL CARBOXYLATION OF ALLYLIC BROMIDES USING A REACTIVE-METAL ANODE, Tetrahedron letters, 36(19), 1995, pp. 3345-3348
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
19
Year of publication
1995
Pages
3345 - 3348
Database
ISI
SICI code
0040-4039(1995)36:19<3345:RSOBAB>2.0.ZU;2-R
Abstract
Electrolysis of gamma-mono and disubstituted allylic bromides in the p resence of atmospheric pressure of carbon dioxide using a platinum cat hode and a magnesium anode gave regioselectively the corresponding gam ma-mono and disubstituted beta,gamma-unsaturated carboxylic acids in 3 4-71% yields.