A DIRECT AND A FORMAL TRAPPING OF PROPA-1,2-DIENYLIDENE

1,2-Dibromocyclopropene ring-opens in solution at 0 - 20 degrees C to give 1,2-dibromoprop-2-en-1-ylidene, which is napped by alkenes; the d erived cyclopropanes react efficiently with methyl lithium to produce eth-1-en-1-ylidenecyclopropanes. Reaction of the cyclopropene with met hyl lithium in ether in the presence of an alkene leads to the same al lenes by trapping of the parent allenic carbene, propa-1,2-dienylidene , albeit in low yield.