2-SUBSTITUTED BICYCLO[3.2.1]OCT-2-EN-8-ONES BY CARBONYLATION OF CYCLOHEPTADIENE-DERIVED IRON CARBONYL-COMPLEXES BEARING ALKYL-ALLYL SUBUNITS

Authors
HIRSCHFELDER A EILBRACHT P
Citation
A. Hirschfelder et P. Eilbracht, 2-SUBSTITUTED BICYCLO[3.2.1]OCT-2-EN-8-ONES BY CARBONYLATION OF CYCLOHEPTADIENE-DERIVED IRON CARBONYL-COMPLEXES BEARING ALKYL-ALLYL SUBUNITS, Synthesis, (5), 1995, pp. 587-591
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthesis → ACNP
ISSN journal
00397881
Issue
5
Year of publication
1995
Pages
587 - 591
Database
ISI
SICI code
0039-7881(1995):5<587:2BBCOC>2.0.ZU;2-5
Abstract
Iron carbonyl complexes 7, generated by the reaction of cationic cyclo heptadienyl complex 6 [L = P(OPh)(3)] with appropriate nucleophiles, c an be converted into bicyclooctenones 9 and 10 via carbonylative decom plexation. Treatment of 7 with CO (200 bar) at elevated temperatures y ields the ketones 10 as the main products. Thus, carbonylation is acco mpanied by double bond migration.