Va. Likholobov et al., NEW CARBON-CARBONACEOUS COMPOSITES FOR CATALYSIS AND ADSORPTION, Reaction kinetics and catalysis letters, 54(2), 1995, pp. 381-411
Properties, structural features, and basic principles for the synthesi
s of some new carbon-carbonaceous composite materials (CCM) originatin
g at the Boreskov Institute of Catalysis are discussed. The CCM are sy
nthesized via chemical growth of carbon deposits in a pre-formed porou
s carbon matrix. Among the CCM are: Sibunit produced by supporting pyr
ocarbon (PC) on carbon black granules, carbon filaments (CFC) produced
by decomposition of CH4 over Ni or Ni-Cu catalysts, CFC on Sibunit, C
FC on ultradispersed diamond, and systems such as CFC/CFC, PC/CFC, etc
. Basic mechanisms of structure and texture formation of CCM and some
of their properties as adsorbents and catalyst supports are reported.