CRYSTAL-STRUCTURE OF [SNCL4(PH(2)PCH(2)-C H(2)PPH(2))]CENTER-DOT-CH2CL2

Authors
KUNKEL F DEHNICKE K
Citation
F. Kunkel et K. Dehnicke, CRYSTAL-STRUCTURE OF [SNCL4(PH(2)PCH(2)-C H(2)PPH(2))]CENTER-DOT-CH2CL2, Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 50(5), 1995, pp. 848-850
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur Naturforschung. B, A journal of chemical sciences → ACNP
ISSN journal
09320776
Volume
50
Issue
5
Year of publication
1995
Pages
848 - 850
Database
ISI
SICI code
0932-0776(1995)50:5<848:CO[H>2.0.ZU;2-J
Abstract
[SnCl4(Ph(2)PCH(2)-CH(2)PPh(2))]. CH2Cl2 has been characterized by a c rystal structure determination. Space group P2(1)/c, Z = 4, 5565 obser ved unique reflections with I > 2 sigma(I), R = 0.043. Lattice dimensi ons at -70 degrees C: a = 1141.4(6), b = 2178.3(11), c = 1399.1(7) pm, beta = 108.96(3)degrees. The complex forms monomeric molecules with t he 1,2-bis(diphenylphosphino)ethane as chelating ligand. Bond lengths (average): Sn-P 266.7 pm, Sn-Cl 241.8 pm.