Dp. Sutija et al., TRANSPORT NUMBER DETERMINATION BY THE CONCENTRATION-CELL OPEN-CIRCUITVOLTAGE METHOD FOR OXIDES WITH MIXED ELECTRONIC, IONIC AND PROTONIC CONDUCTIVITY, Solid state ionics, 77, 1995, pp. 167-174
Wagner's theory of mixed conduction has been applied to foreign and na
tive species simultaneously in determining the open-circuit potential
(OCV) of a concentration cell. We present general derivations for the
OCV for mixed conductors containing protonic species, native ions and
electrons and propose experiments for discriminating transport by the
various species.