SYNTHESIS, CONDUCTIVITY AND STRUCTURAL CHARACTERIZATION OF PHOSPHORUSBRONZES ORIGINATING FROM HETEROPOLYACIDS - RELATION WITH SIMILAR PROTON CONTAINING PHASES

Authors
DIMITRIJEVIC RZ COLOMBAN P MIOC UB NEDIC Z TODOROVIC MR TJAPKIN N DAVIDOVIC M
Citation
Rz. Dimitrijevic et al., SYNTHESIS, CONDUCTIVITY AND STRUCTURAL CHARACTERIZATION OF PHOSPHORUSBRONZES ORIGINATING FROM HETEROPOLYACIDS - RELATION WITH SIMILAR PROTON CONTAINING PHASES, Solid state ionics, 77, 1995, pp. 250-256
Citations number
23
Categorie Soggetti
Physics, Condensed Matter","Chemistry Physical
Journal title
Solid state ionics → ACNP
ISSN journal
01672738
Volume
77
Year of publication
1995
Pages
250 - 256
Database
ISI
SICI code
0167-2738(1995)77:<250:SCASCO>2.0.ZU;2-S
Abstract
The phosphorus doped molybdenum oxide compound (P0.18Mo4.00O12.66). is ostructural with molybdite was synthesized in the process of thermally induced phase transformation of 12-molybdophosphoric acid. The synthe sized phases (low and high temperature) and the precursor compound (e- phase) have been characterized by thermal (DTA and TGA), X-ray powder diffraction, electron scanning microscopy and spectroscopic (IR) metho ds. The temperature dependence of electric conductivity sigma(omega--> 0) is discussed. It was concluded that the electronic conductivities o f bronzes obtained from heteropolyacids are very similar to those of c orresponding anhydrous polyacids.