MASS-SELECTED ZEKE-SPECTRA OF FEC2-ANIONS - A SPECTROSCOPIC ACCESS TOINTERMEDIATES IN CATALYTIC REACTIONS OF HYDROCARBONS ON METAL-SURFACES

Authors
DRECHSLER G BASSMANN C BOESL U SCHLAG EW
Citation
G. Drechsler et al., MASS-SELECTED ZEKE-SPECTRA OF FEC2-ANIONS - A SPECTROSCOPIC ACCESS TOINTERMEDIATES IN CATALYTIC REACTIONS OF HYDROCARBONS ON METAL-SURFACES, Zeitschrift fur Naturforschung. A, A journal of physical sciences, 49(12), 1994, pp. 1256-1258
Citations number
12
Categorie Soggetti
Chemistry Physical",Physics
Journal title
Zeitschrift fur Naturforschung. A, A journal of physical sciences → ACNP
ISSN journal
09320784
Volume
49
Issue
12
Year of publication
1994
Pages
1256 - 1258
Database
ISI
SICI code
0932-0784(1994)49:12<1256:MZOF-A>2.0.ZU;2-Y
Abstract
Zero-kinetic-energy (ZEKE) photoelectron spectra of metalcarbide anion s are presented, allowing a high resolution spectroscopic access to in termediates in catalytic reactions of hydrocarbons on metal surfaces. As a first compound, FeC2 (an intermediate of the iron/acetylene syste m) has been chosen. Important for successful ZEKE spectroscopy was a s pecial anion source and the selection by time-of-flight mass spectrome try. In addition, conventional laser induced photo-detachment photoele ctron spectroscopy in combination with our anion source and mass analy zer delivered valuable new information.