On the basis of a continuum multi-fluid description of a plasma, a the
ory is developed of an ionization layer between a plasma in ionization
(Saha) equilibrium and the space-charge sheath near a surface of a ca
thode or of an insulating wall. The crucial parameter determining the
character of the solution is the ratio of the recombination length to
the mean free path ion-neutral species; if this ratio is large, then t
he developed theory is consistent with a conventional diffusion approa
ch. Numerical and asymptotic solutions of a stated problem are obtaine
d. It is found that the problem is solvable only if the degree of ioni
zation does not exceed a certain value, which varies between approxima
tely 0.6 and 1. Beyond this value, the equation of the pressure balanc
e cannot be satisfied and the plasma as a whole in the considered laye
r cannot stay in static equilibrium. A simple approximate formula for
the ion flux is obtained.