ENERGY-LEVELS OF THE WEAKLY INTERACTING RADICALS

Citation
M. Naroznik et J. Niedzielski, ENERGY-LEVELS OF THE WEAKLY INTERACTING RADICALS, Theoretica Chimica Acta, 94(5), 1996, pp. 271-285
Citations number
14
Categorie Soggetti
Chemistry Physical
Journal title
ISSN journal
00405744
Volume
94
Issue
5
Year of publication
1996
Pages
271 - 285
Database
ISI
SICI code
0040-5744(1996)94:5<271:EOTWIR>2.0.ZU;2-5
Abstract
Energy levels of the weakly interacting radicals are estimated on the basis of planar methyl radical interaction as a model. These levels de pend on the given separation r between the centers of mass. The approp riate Schrodinger equation is solved by using the Brillouin-Wigner ser ies method. Analytical forms for the integrals used to estimate matrix elements are derived. The principle of total momentum conservation is strictly obeyed. Some energy levels cannot be estimated as a result o f divergence.