Rs. Davidson et al., ATTEMPTS TO PHOTOSTABILIZE PAPER MADE FROM HIGH-YIELD PULP BY APPLICATION OF UV SCREENS AND CONTROL OF PH, Journal of photochemistry and photobiology. A, Chemistry, 86(1-3), 1995, pp. 275-282
Paper made from bleached chemithermomechanical pulp (CTMP) was treated
with UV absorbers, e.g. 2,4-dihydroxybenzophenone and a 2-(2-hydroxyp
henyl)benzotriazole derivative (Tinuvin 1130) to reduce the tendency o
f the paper to undergo photoyellowing. Whilst some of the UV absorbers
offer some protection, their effect can be enhanced by use in conjunc
tion with a reducing agent (sodium hypophosphite) and by lowering the
pH of the paper by application of potassium dihydrogen phosphate. The
best effect was obtained by using Tinuvin 1130 in combination with bot
h a reducing agent and potassium dihydrogen phosphate. The use of hind
ered phenols in both the presence and absence of thiols offered little
protection to the paper.