CHEMICAL-REACTIONS IN THE SYSTEM MGO-MGCL2-H2O FOLLOWED BY TIME-RESOLVED SYNCHROTRON X-RAY-POWDER DIFFRACTION

Authors
CHRISTENSEN AN NORBY P HANSON JC
Citation
An. Christensen et al., CHEMICAL-REACTIONS IN THE SYSTEM MGO-MGCL2-H2O FOLLOWED BY TIME-RESOLVED SYNCHROTRON X-RAY-POWDER DIFFRACTION, Journal of solid state chemistry, 114(2), 1995, pp. 556-559
Citations number
5
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Journal of solid state chemistry → ACNP
ISSN journal
00224596
Volume
114
Issue
2
Year of publication
1995
Pages
556 - 559
Database
ISI
SICI code
0022-4596(1995)114:2<556:CITSMF>2.0.ZU;2-K
Abstract
The chemical reactions in the system MgO-MgCl2-H2O were investigated b y on-line synchrotron X-ray powder diffraction at temperatures up to 1 00 degrees C. The crystalline reaction products formed were Mg(OH)(2) and MgCl2 . 5Mg(OH)(2) . 8H(2)O. The reaction rates in these heterogen eous systems are strongly dependent upon the concentrations of the mag nesium chloride solutions, the molar ratio MgCl2/MgO, and the temperat ure. (C) 1995 Academic Press, Inc.