SYNTHESIS AND CHARACTERIZATION OF BA2-XBIXCU2O5 LESS-THAN-OR-EQUAL-TO-X-LESS-THAN-OR-EQUAL-TO-1.5)

Citation
Ys. Rao et Cs. Sunandana, SYNTHESIS AND CHARACTERIZATION OF BA2-XBIXCU2O5 LESS-THAN-OR-EQUAL-TO-X-LESS-THAN-OR-EQUAL-TO-1.5), Journal of solid state chemistry, 114(2), 1995, pp. 585-589
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Physical
ISSN journal
00224596
Volume
114
Issue
2
Year of publication
1995
Pages
585 - 589
Database
ISI
SICI code
0022-4596(1995)114:2<585:SACOBL>2.0.ZU;2-5
Abstract
Ba2Cu2O5 and its solid solutions with Bi2O3 have been synthesized and characterized using powder XRD, infrared spectroscopy, and DSC. The or thorhombic unit cell dimensions have been measured with the help of po wder X-ray diffraction. The controversial valence state of copper, exa mined through electron paramagnetic resonance, was found to be divalen t. The structural and magnetic resonance results are discussed in deta il. (C) 1995 Academic Press, Inc.