D. Viehland et al., STRUCTURE-PROPERTY RELATIONSHIPS IN STRONTIUM BARIUM NIOBATE .1. NEEDLE-LIKE NANOPOLAR DOMAINS AND THE METASTABLY-LOCKED INCOMMENSURATE STRUCTURE, Philosophical magazine. A. Physics of condensed matter. Defects and mechanical properties, 71(2), 1995, pp. 205-217
Transmission electron microscopy investigations have been performed on
Sr2Ba1-xNb2O6 (SBN (x)(1 - x)). Bright-field imaging of (100)-oriente
d SBN 60/40 and 75/25 crystals revealed nanopolar domains with a stron
g shape anisotropy. The morphology of the nanopolar domains was needle
like. Selected area electron diffraction (SAED) patterns revealed the
existence of 1/x[110] incommensurate modulations. Dark-field imaging
of the incommensurate reflections found the existence of nanometre-siz
ed ferroelastic domains. Diffuse scattering was observed in the SAED p
atterns along the (100) direction. This diffuse scattering is believed
to arise due to strain gradient interactions between the A-site catio
n distribution and the incommensuration.