LEWIS ACIDIC LEWIS BASIC CHARACTER OF THE BIS(TRIPHENYLTIN) SUCCINATEMOIETY IN THE HEXANUCLEAR COMPLEX, [BIS(TRIPHENYLTIN) SUCCINATE-CENTER-DOT-2QUINOLINE N-OXIDE]CENTER-DOT-2[BIS(TRIPHENYLTIN) SUCCINATE]

Authors
NG SW DAS VGK
Citation
Sw. Ng et Vgk. Das, LEWIS ACIDIC LEWIS BASIC CHARACTER OF THE BIS(TRIPHENYLTIN) SUCCINATEMOIETY IN THE HEXANUCLEAR COMPLEX, [BIS(TRIPHENYLTIN) SUCCINATE-CENTER-DOT-2QUINOLINE N-OXIDE]CENTER-DOT-2[BIS(TRIPHENYLTIN) SUCCINATE], Zeitschrift fur Kristallographie, 210(2), 1995, pp. 133-136
Citations number
17
Categorie Soggetti
Crystallography
Journal title
Zeitschrift fur Kristallographie → ACNP
ISSN journal
00442968
Volume
210
Issue
2
Year of publication
1995
Pages
133 - 136
Database
ISI
SICI code
0044-2968(1995)210:2<133:LALBCO>2.0.ZU;2-Z
Abstract
The crystal structure of [bis(triphenyltin) succinate.2quinoline N-oxi de].2[bis(triphenyltin) succinate], C138H116N2O14Sn6, (C2/c, a = 23.32 0(3) Angstrom, b = 12.007(1) Angstrom, c = 42.711(8) Angstrom, beta = 92.285(8)degrees) consists of a hexanuclear molecule whose bis(triphen yltin) succinate.2quinoline N-oxide (Sn1-O = 2.177(7) Angstrom, Sn1<-- O = 2.345(9) Angstrom) moiety is bridged through its carbonyl atoms to two symmetry-related bis(triphenyltin) succinate entities. In the bis (triphenyltin) succinate unit, one tin atom is five-coordinated (Sn2-O = 2.112(9) Angstrom, Sn2<--O = 2.409(8) Angstrom) in a trigonal bipyr amidal geometry and the other is four-coordinated (Sn3-O = 2.04(1) Ang strom) in a tetrahedral geometry.