CORRELATION-INDUCED NONMONOTONIC BEHAVIOR OF REVERSIBLE CHEMICAL-REACTIONS

Authors
OSHANIN G MOGUTOV A MOREAU M BURLATSKY SF
Citation
G. Oshanin et al., CORRELATION-INDUCED NONMONOTONIC BEHAVIOR OF REVERSIBLE CHEMICAL-REACTIONS, Journal of molecular liquids, 63(1-2), 1995, pp. 175-197
Citations number
34
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
Journal of molecular liquids → ACNP
ISSN journal
01677322
Volume
63
Issue
1-2
Year of publication
1995
Pages
175 - 197
Database
ISI
SICI code
0167-7322(1995)63:1-2<175:CNBORC>2.0.ZU;2-9
Abstract
We consider the kinetics of reversible recombination reaction A + B do uble left right arrow C, involving diffusive particles A, B and C. We show that spatial fluctuations in particles concentrations induce non- monotonic power-law approach to the equilibrium in place of the monoto nic exponential on time relaxation, predicted by mean-field approximat ions.