HYDROLYSIS OF SCHIFF-BASES IN (CTAB-CHCL3-H2O) REVERSED MICELLES - ROLE OF SPACERS

Authors
SENAPATI S DASH PK MISHRA BK BEHERA GB
Citation
S. Senapati et al., HYDROLYSIS OF SCHIFF-BASES IN (CTAB-CHCL3-H2O) REVERSED MICELLES - ROLE OF SPACERS, Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical, 34(3), 1995, pp. 227-229
Citations number
19
Categorie Soggetti
Chemistry
Journal title
Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical → ACNP
ISSN journal
03764710
Volume
34
Issue
3
Year of publication
1995
Pages
227 - 229
Database
ISI
SICI code
0376-4710(1995)34:3<227:HOSI(R>2.0.ZU;2-8
Abstract
The schiff bases of the type (p-C16H33O-C6H4CH = N)(2)(CH2)(m) (1, m = 0, 2, 3, 4 and 6) and the ortho isomer (2, m = 0, 2, 4, 6) have been synthesized and the hydrolysis of these compounds have been studied in CTAB-CHCl3-H2O reversed micellar system under acidic condition. Signi ficant variation of the reaction rate has been observed due to variati on in the number of methylene groups in the spacer and due to the chan ge in the position of the cetyloxy group. Difference in the rate of di sappearance of schiff base and appearance of the product is ascribed t o a mechanism involving a carbinolamine intermediate.