A FOURIER-TRANSFORM INFRARED AND LASER-RAMAN SPECTROSCOPIC INVESTIGATION OF 4,4'-BIPYRIDYL-TRANSITION METAL(II) TETRACYANONICKELATE CLATHRATES

Authors
AKYUZ S AKYUZ T DAVIES JED
Citation
S. Akyuz et al., A FOURIER-TRANSFORM INFRARED AND LASER-RAMAN SPECTROSCOPIC INVESTIGATION OF 4,4'-BIPYRIDYL-TRANSITION METAL(II) TETRACYANONICKELATE CLATHRATES, Journal of inclusion phenomena and molecular recognition in chemistry, 26(1-3), 1996, pp. 111-117
Citations number
15
Categorie Soggetti
Chemistry,Crystallography
Journal title
Journal of inclusion phenomena and molecular recognition in chemistry → ACNP
ISSN journal
09230750
Volume
26
Issue
1-3
Year of publication
1996
Pages
111 - 117
Database
ISI
SICI code
0923-0750(1996)26:1-3<111:AFIALS>2.0.ZU;2-K
Abstract
The FT-IR and Raman spectra are reported of M(4, 4'-bipyridyl)Ni(CN)(4 ) . nG (where M = Mn, Fe, Co, Cu or Zn and G = benzene or aniline; n = 0-2) clathrates. The host structure consists of a three-dimensional r igid lattice formed by infinite polymeric layers of {M-Ni(CN)(4)}(infi nity) and 4, 4'-bipyridyl bridges between the metal (M) atoms of the a djacent polymeric layers. Bidentate 4, 4'-bipyridyl molecules are foun d to be centrosymmetric in the structure.