Authors
Citation
T. Kitazawa, THE STRUCTURE OF THE MINERALOMIMETIC CADMIUM CYANIDE-DIMETHYL CARBONATE CLATHRATE, Journal of inclusion phenomena and molecular recognition in chemistry, 26(1-3), 1996, pp. 153-159
Citations number
25
Categorie Soggetti
Chemistry,Crystallography
ISSN journal
09230750
Volume
26
Issue
1-3
Year of publication
1996
Pages
153 - 159
Database
ISI
SICI code
0923-0750(1996)26:1-3<153:TSOTMC>2.0.ZU;2-6
Abstract
Cd(CN)(2) .(CH3O)(2)CO (1) contains a mineralomimetic framework of Cd(
CN)(2) analogous to the low temperature form of cristobalite. The host
framework is isostructural to those of previously reported Cd(CN)(2)
. G compounds (G = CHCl2CH2Cl 2, (CH3)(2)CHBr 3). The dimethyl carbona
te molecules in the adamantane-like cage display orientation disorder
associated with the location of the carbonyl oxygen atom.