SYNTHESIS OF A NEW EXTENDED PI-DONOR WITH 1,4-OXATHIANE ANNULATION

Authors
HELLBERG J BALODIS K MOGE M KORALL P VONSCHUTZ JU
Citation
J. Hellberg et al., SYNTHESIS OF A NEW EXTENDED PI-DONOR WITH 1,4-OXATHIANE ANNULATION, Journal of materials chemistry, 7(1), 1997, pp. 31-34
Citations number
13
Categorie Soggetti
Chemistry Physical","Material Science
Journal title
Journal of materials chemistry → ACNP
ISSN journal
09599428
Volume
7
Issue
1
Year of publication
1997
Pages
31 - 34
Database
ISI
SICI code
0959-9428(1997)7:1<31:SOANEP>2.0.ZU;2-4
Abstract
Bis(1,4-oxathiane-2,3-diylditho)tetrathiafulvalene 7 (TOET) is synthes ised in four steps from 1,4-oxathiane. Compound 7 shows two reversible redox couples at 0.56 and 0.90 V vs. SCE. Analysis of NMR spectra com bined with energy minimisation calculations indicated that at least th ree isomers of TOET should be present in solution. TOET forms a charge -transfer complex with TCNQ which shows a conductivity of 3 x 10(-3) S cm(-1).