THE INVENTION OF RADICAL REACTIONS .34. HOMOLOGATION OF CARBOXYLIC-ACIDS TO ALPHA-KETO CARBOXYLIC-ACIDS BY BARTON-ESTER BASED RADICAL-CHAINCHEMISTRY

Authors
BARTON DHR CHERN CY JASZBERENYI JC
Citation
Dhr. Barton et al., THE INVENTION OF RADICAL REACTIONS .34. HOMOLOGATION OF CARBOXYLIC-ACIDS TO ALPHA-KETO CARBOXYLIC-ACIDS BY BARTON-ESTER BASED RADICAL-CHAINCHEMISTRY, Tetrahedron, 51(7), 1995, pp. 1867-1886
Citations number
108
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
51
Issue
7
Year of publication
1995
Pages
1867 - 1886
Database
ISI
SICI code
0040-4020(1995)51:7<1867:TIORR.>2.0.ZU;2-K
Abstract
Carboxylic acids can be transformed into the homologous alpha-keto aci ds by Barton-ester based radical chemistry. This method was especially successful when ethyl alpha-trifluoroacetoxy acrylate was used as a r adical trap.