NEW ANTIFEEDANT NEOCLERODANE TRIOL - SEMISYNTHESIS AND ANTIFEEDANT ACTIVITY OF NEOCLERODANE DITERPENOIDS

Authors
URONES JG BASABE P LITHGOW AM MARCOS IS JIMENEZ A DIEZ D GOMEZ A WHITE AJP WILLIAMS DJ SIMMONDS MSJ BLANEY WM
Citation
Jg. Urones et al., NEW ANTIFEEDANT NEOCLERODANE TRIOL - SEMISYNTHESIS AND ANTIFEEDANT ACTIVITY OF NEOCLERODANE DITERPENOIDS, Tetrahedron, 51(7), 1995, pp. 2117-2128
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
51
Issue
7
Year of publication
1995
Pages
2117 - 2128
Database
ISI
SICI code
0040-4020(1995)51:7<2117:NANT-S>2.0.ZU;2-5
Abstract
Methyl 2 alpha 3 beta,4 beta-trihydroxy-neo-clerodan-15-oate was isola ted from the acid fraction of Cistus populifolius and its structure de termined by semisynthesis and confirmed by X-ray diffraction. Three ot her triols (2, 3 and 4) and an intermediate diol (5) were also synthes ized as potential antifeedants. The functional groups and stereochemis try for antifeedancy are discussed.