G. Reginato et al., STANNYLCUPRATION OF GAMMA-HETEROSUBSTITUTED ACETYLENIC ESTERS - A NEWROUTE TO 4-STANNYLATED 5 MEMBERED N-HETEROCYCLES AND O-HETEROCYCLES, Tetrahedron, 51(7), 1995, pp. 2129-2136
4-Tributylstannyl,2-(5H)-furanone and pyrrolone have been prepared in
good yields by addition of mixed stannylcuprate reagent on gamma-amino
and gamma-hydroxy acetylenic esters. The use of these compounds as us
eful intermediates for the selective functionalization of these hetero
cyclic, rings is discussed.