STRUCTURAL STUDY ON QUASI-PHOSPHONIUM SALTS CONTAINING PHOSPHORUS OXYGEN, PHOSPHORUS-NITROGEN AND PHOSPHORUS SULFUR BONDS

Authors
IMRIE C MODRO TA VANROOYEN PHG WAGENER CCP WALLACE K HUDSON HR MCPARTLIN M NASIRUN JB POWROZNYK L
Citation
C. Imrie et al., STRUCTURAL STUDY ON QUASI-PHOSPHONIUM SALTS CONTAINING PHOSPHORUS OXYGEN, PHOSPHORUS-NITROGEN AND PHOSPHORUS SULFUR BONDS, Journal of physical organic chemistry, 8(1), 1995, pp. 41-46
Citations number
22
Categorie Soggetti
Chemistry Physical","Chemistry Inorganic & Nuclear
Journal title
Journal of physical organic chemistry → ACNP
ISSN journal
08943230
Volume
8
Issue
1
Year of publication
1995
Pages
41 - 46
Database
ISI
SICI code
0894-3230(1995)8:1<41:SSOQSC>2.0.ZU;2-X
Abstract
The crystal and molecular structures of six quasi-phosphonium salts co ntaining phosphorus-heteroatom (heteroatom = oxygen, sulphur or nitrog en) bonds were determined. Comparison of the molecular parameters obta ined with those available for reference structures demonstrated that t he 'double bond' character for the P+ - Y bond decreases in the order Y = N much greater than O > S.